Hydrogenation of carbon monoxide adsorbed on supported platinum group metals was studied by the in-situ IR spectroscopy and the temperature programmed desorption (TPD) method using hydrogen as a carrier gas. The main product of hydrogenation was methane, and the TPD gave the spectra of methane formation which showed peaks between 150°C …
view more1999311 · Adsorbed hydrogen atoms are known to be capable of both promoting and inhibiting self-diffusion 3,4,5,6,7, offering the prospect of using adsorbed gases to control growth or sintering processes 8 ...
view more202277 · The role played by adsorbed OH in the methanol electro-oxidation to CO on platinum in aqueous medium is supported by DFT calculations, as well as the reason why this reaction is not observed in ...
view more2023527 · The inclusion of platinum-group metals for CO2 reduction electrocatalyst design may trigger the unwanted hydrogen evolution reaction. However, here the authors show that single-atom Pd and Pt on ...
view more2005929 · The adsorption of NH3 (on top) and NH2 (bridge) is more favorable on Pt (100) than on Pt (111), while similar adsorption energies were computed for NH (hollow) and N (hollow) on both surfaces. The remarkably lower adsorption energy of NH2 over Pt (111) as compared with Pt (100) (the difference being approximately 0.7 eV) can be related to ...
view moreSYNOPSIS. The research presented in this paper investigated the practical aspects of the recovery of platinum group metals (PGMs) from a dilute cyanide leach solution containing base metals, in a manner similar to that used for gold extraction in a typical CIP process, and focuses on both the adsorption and elution stages.
view moreAmmonia Dehydrogenation over Platinum-Group Metal Surfaces. Structure, Stability, and Reactivity of Adsorbed NHx Species. ... J. M. Ricart, and, J. Pérez-Ramírez. DFT Characterization of Adsorbed NHx Species on Pt(100) and Pt(111) Surfaces. The Journal of Physical Chemistry B 2005, 109 (38) , 18061-18069.
view more2000229 · Ammonia Dehydrogenation over Platinum-Group Metal Surfaces. Structure, Stability, and Reactivity of Adsorbed NHx Species. The Journal of Physical Chemistry C 2007, 111 (2) , 860-868. DOI: 10.1021/jp064742b. Jinlong ... DFT Characterization of Adsorbed NHx Species on Pt(100) and Pt(111) Surfaces.
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